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We have developed a series of new technologies and materials with independent intellectual property such as magnesia hercynite bricks, low thermal conductivity anti-spalling bricks, low thermal conductivity magnesia alumina spinel bricks and high anti-corrosion special magnesia alumina spinel bricks, whose performances have held a safe lead domestically and which have been applied in European rotary kilns in batches. These materials are currently the only Chinese refractories applied in European cement rotary kilns which have similar working conditions to our second generation cement rotary kilns.